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Hedione® (Firmenich)

Description

A truly revolutionary molecule in modern perfumery, this ingredient provides an unparalleled radiant and diffusive effect. The odor profile of Hedione® (Firmenich) is exceptionally elegant and complex, characterized by a transparent, airy jasmine quality. It unfolds with delicate citrus facets reminiscent of lemon and grapefruit, supported by a subtle green, watery freshness. A natural, slightly sweet and oily character rounds out its profile, creating a sense of luminosity and space within a composition. First synthesized in the late 1950s, this ester, known chemically as Methyl dihydrojasmonate, is composed of different isomers, where the cis-isomer ratio is critical for defining the intensity of its signature floral bloom.

Its remarkable versatility makes it a fundamental component across a vast spectrum of fragrance creations. From fine fragrances to functional perfumery, Methyl dihydrojasmonate is utilized to impart a smooth, well-rounded character. Recommended usage levels are broad, ranging from subtle touches at 1-5% to forming a significant part of the structure at 20% or more. It acts as a peerless blender, enhancing the diffusion of floral bouquets while brightening top notes and adding a dewy, tropical aspect to fruity accords. When paired with citrus oils, it extends their freshness, and in combination with woody and musky notes, it contributes a sophisticated airiness and volume that elevates the entire fragrance.

General Information

Alt NameMethyl dihydrojasmonate
CategoryAromatic Compound
IUPAC Namemethyl 2-(3-oxo-2-pentylcyclopentyl)acetate
CAS Number24851-98-7
Molecular Weight226.31 g/mol
Canonical SMILESCCCCCC1C(CCC1=O)CC(=O)OC

Organoleptic Properties

Odor Family
Floral
Odor Strength
1
2
3
4
5
Odor DescriptionCitrus, Floral, Fruity, Grapefruit, Green, Jasmin, Lactonic, Lemon, Natural, Oily, Sweet, Tropical, Woody
Usage Level30% in the fragrance concentrate
Substantivity336 hours at 100%

Physical Properties

AppearanceColorless to pale yellow clear oily liquid (est)
Specific Gravity0.997 to 1.006 @ 25 °C.
Pounds per Gallon8.296 to 8.371
Refractive Index1.458 to 1.462 @ 20 °C.
Vapor Pressure0.001 mmHg @ 25 °C. (est)
Boiling Point109 to 112 °C. @ 0.2 mm Hg
Flash Point235 °F. TCC ( 113 °C. )
XLogP2.7
Acid Value2 max. KOH/g
Shelf Life36 months if stored properly
StorageStore in cool, dry place in tightly sealed containers, protected from heat and light.

IFRA

CategoryFlavor and fragrance agents

Safety Information

PictogramsGHS07: Harmful
Hazard StatementH302 - Harmful if swallowed
H401 - Toxic to aquatic life
Precautionary StatementP264 - Wash … thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P273 - Avoid release to the environment
P301 + P312 - IF SWALLOWED: Call a POISON CENTER/doctor/…/if you feel unwell
P330 - Rinse mouth
P501 - Dispose of contents/container in accordance with local/regional/national/international regulations.
S-phrasesS02 - Keep out of the reach of children
S24/25 - Avoid contact with skin and eyes
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