An exceptionally fresh and radiant floral character defines this essential perfumery material. Its elegant profile is reminiscent of a transparent, luminous jasmine, brightened with natural-smelling citrus facets of lemon and grapefruit, and a subtle green nuance. As a high cis-isomer grade of methyl dihydrojasmonate, Hedione® HC from Firmenich offers a more powerful, purely floral, and less oily profile than its classic counterpart. This specific isomeric composition is key to its prized effect, delivering a diffusive and airy quality that feels both incredibly modern and timeless. First synthesized in the late 1950s, its introduction revolutionized perfumery by providing an entirely new texture and radiance previously unattainable.
The versatile nature of this compound allows for its use in nearly every olfactive family, where it imparts remarkable bloom, volume, and a seamless connection between fragrance notes. In compositions, it acts as an exalting agent, enhancing the diffusion of other materials and adding a sophisticated lift from the top notes through the heart. Recommended usage levels are exceptionally broad, ranging from just one or two percent to add a subtle sparkle, to over thirty percent where it forms the structural backbone of a fragrance. It combines beautifully with citrus accords to boost freshness, enriches floral bouquets with unparalleled naturalness, and provides a juicy, watery effect to fruity and tropical creations.
| Category | Aromatic Compound |
|---|---|
| IUPAC Name | methyl 2-(3-oxo-2-pentylcyclopentyl)acetate |
| CAS Number | 24851-98-7 |
| Molecular Weight | 226.31 g/mol |
| Canonical SMILES | CCCCCC1C(CCC1=O)CC(=O)OC |
| Odor Family | Floral |
|---|---|
| Odor Strength | 1 2 3 4 5 |
| Odor Description | Citrus, Floral, Fruity, Grapefruit, Green, Jasmin, Lactonic, Lemon, Natural, Oily, Sweet, Tropical, Woody |
| Usage Level | 30% in the fragrance concentrate |
| Substantivity | 400 hours at 100% |
| Appearance | Colorless to pale yellow clear oily liquid (est) |
|---|---|
| Specific Gravity | 0.997 to 1.006 @ 25 °C. |
| Pounds per Gallon | 8.296 to 8.371 |
| Refractive Index | 1.458 to 1.462 @ 20 °C. |
| Vapor Pressure | 0.001 mmHg @ 25 °C. (est) |
| Boiling Point | 109 to 112 °C. @ 0.2 mm Hg |
| Flash Point | 235 °F. TCC ( 113 °C. ) |
| XLogP | 2.7 |
| Acid Value | 2 max. KOH/g |
| Shelf Life | 24 months if stored properly |
| Storage | Store in cool, dry place in tightly sealed containers, protected from heat and light. |
| Category | Flavor and fragrance agents |
|---|
| Pictograms | |
|---|---|
| Hazard Statement | H302 - Harmful if swallowed H401 - Toxic to aquatic life |
| Precautionary Statement | P264 - Wash … thoroughly after handling P270 - Do not eat, drink or smoke when using this product P273 - Avoid release to the environment P301 + P312 - IF SWALLOWED: Call a POISON CENTER/doctor/…/if you feel unwell P330 - Rinse mouth P501 - Dispose of contents/container in accordance with local/regional/national/international regulations. |
| S-phrases | S02 - Keep out of the reach of children S24/25 - Avoid contact with skin and eyes |