Helional (IFF)

Description

Green, floral (cyclamen) with top notes of ozone and new mown hay.

General Information

Alt Name	Ocean propanal
Category	Aromatic Compound
IUPAC Name	3-(1,3-benzodioxol-5-yl)-2-methylpropanal
CAS Number	1205-17-0
Molecular Weight	192.21 g/mol
Canonical SMILES	CC(CC1=CC2=C(C=C1)OCO2)C=O

Organoleptic Properties

Odor Family	Floral
Odor Strength	1 2 3 4 5
Odor Description	Cyclamen, Fresh, Green, Hay, Ozone, Watery
Usage Level	2% in the fragrance concentrate
Substantivity	64 hours at 100%

Physical Properties

Appearance	Pale yellow to yellow clear oily liquid (est)
Specific Gravity	1.161 to 1.167 @ 25 °C.
Pounds per Gallon	9.661 to 9.711
Refractive Index	1.531 to 1.536 @ 20 °C.
Vapor Pressure	0.003 mm/Hg @ 25 °C. (est)
Boiling Point	282 to 284 °C. @ 760 mm Hg
Flash Point	> 200 °F. TCC ( > 93.33 °C. )
XLogP	2.2
Acid Value	5 max. KOH/g
Shelf Life	24 months if stored properly
Storage	Store in cool, dry place in tightly sealed containers, protected from heat and light.

IFRA

Standard

https://ifrafragrance.org/standards/IFRA_STD_059.pdf

Category

Flavor and fragrance agents

Critical Effect

Sensitization

Restrictions

Usage limits in the finished product

Cat. 1Category 1:	0.12 %
Cat. 2Category 2:	0.25 %
Cat. 3Category 3:	0.039 %
Cat. 4Category 4:	2.6 %
Cat. 5ACategory 5A:	0.39 %
Cat. 5BCategory 5B:	0.077 %
Cat. 5CCategory 5C:	0.077 %
Cat. 5DCategory 5D:	0.026 %
Cat. 6Category 6:	0.62 %

Cat. 7ACategory 7A:	0.077 %
Cat. 7BCategory 7B:	0.077 %
Cat. 8Category 8:	0.026 %
Cat. 9Category 9:	0.15 %
Cat. 10ACategory 10A:	0.15 %
Cat. 10BCategory 10B:	0.62 %
Cat. 11ACategory 11A:	0.026 %
Cat. 11BCategory 11B:	0.026 %
Cat. 12Category 12:	12 %

Safety Information

Pictograms
Hazard Statement	H303 - May be harmful if swallowed H313 - May be harmful in contact with skin H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H320 - Causes eye irritation H411 - Toxic to aquatic life with long-lasting effects
Europe Standard Hazard	N - Dangerous for the environment Xi - Irritant
Precautionary Statement	P261 - Avoid breathing dust/fumes/gas/mist/vapours/spray P264 - Wash … thoroughly after handling P272 - Contaminated work clothing should not be allowed out of the workplace P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P302 + P352 - IF ON SKIN: Wash with plenty of water/… P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing P312 - Call a POISON CENTER/ doctor/…/if you feel unwell P333 + P313 - If skin irritation or a rash occurs: Get medical advice/attention P337 + P313 - If eye irritation persists get medical advice/attention P362 - Take off contaminated clothing P391 - Collect spillage P501 - Dispose of contents/container in accordance with local/regional/national/international regulations.
R-phrases	R36/38 - Irritating to eyes and skin R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
S-phrases	S02 - Keep out of the reach of children S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S36 - Wear suitable protective clothing S61 - Avoid release to the environment. Refer to special instructions/safety data sheet

References

Official Website	https://iff-v2.prod-use1.investis.com/~/media/Files/I/IFF-V2/documents/ingredients-files/helional.pdf
TGSC	http://www.thegoodscentscompany.com/data/rw1007732.html
PubChem	https://pubchem.ncbi.nlm.nih.gov/compound/64805