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Lilial® (Givaudan)

Description

An intensely fresh and powerful floralcy, marked by significant watery and green undertones, evokes the classic scent of muguet. This core lily-of-the-valley character is clean and diffusive, capturing a dewy, vibrant petal-like quality that brings life to a composition. Subtle complexities emerge through a soft, powdery background and a faint, almost hidden cumin-like nuance that adds a unique warmth and depth. The overall effect of the ingredient, known commercially as Lilial®, is one of impressive radiance, imparting a realistic and humid floral signature to any blend.

For decades, its versatility made it a workhorse for building a wide array of floral accords. It was particularly recommended for conferring tenacity and realism to muguet, linden-blossom, and cyclamen compositions, where its presence could create a blooming, voluminous effect. In these applications, this aldehyde, chemically known as p-tert-Butyl-alpha-methylhydrocinnamic aldehyde, blended seamlessly with materials like hydroxycitronellal and cyclamen aldehyde to create complete bouquets. Due to significant regulatory reclassifications, its use in modern perfumery is now heavily restricted or prohibited in many regions, making it a legacy material in the floral palette.

General Information

CategoryAromatic Compound
IUPAC Name3-(4-tert-butylphenyl)butanal
CAS Number80-54-6
Molecular Weight204.31 g/mol
Canonical SMILESCC(CC=O)C1=CC=C(C=C1)C(C)(C)C

Organoleptic Properties

Odor Family
Floral
Odor Strength
1
2
3
4
5
Odor DescriptionCumin, Floral, Green, Muguet, Powdery, Watery
Usage Level1% in the fragrance concentrate
Substantivity236 hours at 100%

Physical Properties

AppearanceColorless to pale yellow clear oily liquid (est)
Specific Gravity0.942 to 0.947 @ 25 °C.
Pounds per Gallon7.838 to 7.88
Refractive Index1.503 to 1.506 @ 20 °C.
Vapor Pressure0.005 mmHg @ 25 °C. (est)
Boiling Point250 to 251 °C. @ 750 mm Hg
Flash Point210 °F. TCC ( 98.89 °C. )
XLogP3.6
Acid Value2 max. KOH/g
Shelf Life24 months if stored properly
StorageStore in cool, dry place in tightly sealed containers, protected from heat and light.

IFRA

Standardhttps://ifrafragrance.org/standards/IFRA_STD_015.pdf
CategoryFragrance agents
Critical EffectDermal sensitization and systemic toxicity
Restrictions
Usage limits in the finished product
Cat. 1Category 1:0 %
Cat. 2Category 2:0.09 %
Cat. 3Category 3:0.04 %
Cat. 4Category 4:1.4 %
Cat. 5ACategory 5A:0.06 %
Cat. 5BCategory 5B:0.05 %
Cat. 5CCategory 5C:0.05 %
Cat. 5DCategory 5D:0.017 %
Cat. 6Category 6:0 %
Cat. 7ACategory 7A:0.04 %
Cat. 7BCategory 7B:0.04 %
Cat. 8Category 8:0.017 %
Cat. 9Category 9:0.1 %
Cat. 10ACategory 10A:0.1 %
Cat. 10BCategory 10B:0.63 %
Cat. 11ACategory 11A:0.017 %
Cat. 11BCategory 11B:0.017 %
Cat. 12Category 12:16 %

Safety Information

PictogramsGHS07: HarmfulGHS09: Environmental HazardGHS08: Health Hazard
Hazard StatementH302 - Harmful if swallowed
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H361 - Suspected of damaging fertility or the unborn child
H401 - Toxic to aquatic life
H411 - Toxic to aquatic life with long-lasting effects
Precautionary StatementP201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P261 - Avoid breathing dust/fumes/gas/mist/vapours/spray
P264 - Wash … thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P272 - Contaminated work clothing should not be allowed out of the workplace
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301 + P312 - IF SWALLOWED: Call a POISON CENTER/doctor/…/if you feel unwell
P302 + P352 - IF ON SKIN: Wash with plenty of water/…
P308 + P313 - If exposed: Call a POISON CENTER or doctor/physician
P330 - Rinse mouth
P333 + P313 - If skin irritation or a rash occurs: Get medical advice/attention
P362 - Take off contaminated clothing
P391 - Collect spillage
P405 - Store locked up
P501 - Dispose of contents/container in accordance with local/regional/national/international regulations.
R-phrasesR22 - Harmful if swallowed
R36/38 - Irritating to eyes and skin
R43 - May cause sensitisation by skin contact
S-phrasesS02 - Keep out of the reach of children
S24/25 - Avoid contact with skin and eyes
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S37 - Wear suitable gloves
Europe Standard HazardXn - Harmful
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