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Triplal® (IFF)

Description

Green, Leafy, Floral, Powerful. Powerful, green, grass odor that connotes the concentrated refreshing tartness of lemon and bergamot peels. Triplal® is a key product in many modern compositions for its extremely natural green character. It blends beautifully with fruity, citrus, agrestic, floral compositions where it imparts its unique vibrant quality. It is also used to enrich and reinforce classic green notes.

General Information

Alt Name2,4-ivy carbaldehyde
CategoryAromatic Compound
IUPAC Name2,4-dimethylcyclohex-3-ene-1-carbaldehyde
CAS Number68039-49-6
Molecular Weight138.21 g/mol
Canonical SMILESCC1C=C(CCC1C=O)C

Organoleptic Properties

Odor Family
Green
Odor Strength
1
2
3
4
5
Odor DescriptionAldehydic, Cortex, Floral, Green, Leafy, Peely, Tart
Usage Level0.1% in the fragrance concentrate
Substantivity4 hours at 100%

Physical Properties

AppearanceColorless to pale yellow clear liquid (est)
Specific Gravity0.932 to 0.94 @ 25 °C.
Pounds per Gallon7.755 to 7.822
Refractive Index1.469 to 1.475 @ 20 °C.
Vapor Pressure0.578 mmHg @ 25 °C. (est)
Boiling Point196 °C. @ 760 mm Hg
Flash Point151 °F. TCC ( 66.11 °C. )
XLogP1.4
Acid Value5 max. KOH/g
Shelf Life12 months if stored properly
StorageStore in cool, dry place in tightly sealed containers, protected from heat and light.

IFRA

Standardhttps://ifrafragrance.org/standards/IFRA_STD_030.pdf
CategoryFlavor and fragrance agents
Critical EffectDermal sensitization
Restrictions
Usage limits in the finished product
Cat. 1Category 1:0.45 %
Cat. 2Category 2:0.14 %
Cat. 3Category 3:2.7 %
Cat. 4Category 4:2.5 %
Cat. 5ACategory 5A:0.64 %
Cat. 5BCategory 5B:0.64 %
Cat. 5CCategory 5C:0.64 %
Cat. 5DCategory 5D:0.64 %
Cat. 6Category 6:1.5 %
Cat. 7ACategory 7A:5.2 %
Cat. 7BCategory 7B:5.2 %
Cat. 8Category 8:0.27 %
Cat. 9Category 9:4.9 %
Cat. 10ACategory 10A:18 %
Cat. 10BCategory 10B:18 %
Cat. 11ACategory 11A:9.8 %
Cat. 11BCategory 11B:9.8 %
Cat. 12Category 12:100%

Safety Information

PictogramsGHS07: HarmfulGHS09: Environmental Hazard
Hazard StatementH227 - Combustible liquid
H303 - May be harmful if swallowed
H313 - May be harmful in contact with skin
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H320 - Causes eye irritation
H401 - Toxic to aquatic life
H411 - Toxic to aquatic life with long-lasting effects
Europe Standard HazardN - Dangerous for the environment
Xi - Irritant
Precautionary StatementP210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P261 - Avoid breathing dust/fumes/gas/mist/vapours/spray
P264 - Wash … thoroughly after handling
P272 - Contaminated work clothing should not be allowed out of the workplace
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 - IF ON SKIN: Wash with plenty of water/…
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing
P312 - Call a POISON CENTER/ doctor/…/if you feel unwell
P333 + P313 - If skin irritation or a rash occurs: Get medical advice/attention
P337 + P313 - If eye irritation persists get medical advice/attention
P362 - Take off contaminated clothing
P370 + P378 - In case of fire: Use … to extinguish
P391 - Collect spillage
P403 + P235 - Store in a well ventilated place. Keep cool
P501 - Dispose of contents/container in accordance with local/regional/national/international regulations.
R-phrasesR36/38 - Irritating to eyes and skin
R43 - May cause sensitisation by skin contact
R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
S-phrasesS02 - Keep out of the reach of children
S24 - Avoid contact with skin
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S37 - Wear suitable gloves
S61 - Avoid release to the environment. Refer to special instructions/safety data sheet
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